|Validation of HPLC analytical method for determination of biogenic amines in agricultural products|
Hyeock Yoon, Jae-Hyung Mah
An analytical method was validated for the quantitative determination of biogenic amines (BA) in agricultural products. The validation results fulfill AOAC criteria and recommendations. This method has been applying to analyze BA in agricultural products for a total dietary survey in Korea.
|Non-target Screening of Contaminants in Paper-paperboard for Food Contact Materials|
Lukas Vapenka*, Adam Vavrous**, Lenka Votavova*, Kristina Kejlova**, Jaroslav Dobias*, Jitka Sosnovcova**
The aim of this work was non-targeted screening of xenobiotics in paper and paperboard packaging materials used for food packaging in the Czech Republic.
|Development of an Analytical Strategy for Simultaneous Determination of Multiple Contaminants in Paper Food Packaging|
Adam Vavrouš (1), Lukáš Vápenka (2), Kristina Kejlová (1), Jitka Sosnovcová (1), Dagmar Jírová (1)
We developed a method for simultaneous determination of polycyclic aromatic hydrocarbons, polyfluorinated compounds, ink photoinitiators, phthalates and bisphenols in paper food packaging employing GC–MS/MS and HPLC–MS/MS.
|METHOD DEVELOPMENT FOR THE SIMULTANEOUS DETERMINATION OF METHYLMERCURY AND INORGANIC MERCURY IN SEAFOOD|
Sergio Carneado, Ariane V. Zmozinski, Carmen Ibáñez-Palomino, Àngels Sahuquillo, José Fermín López-Sánchez, Márcia M. da Silva
This work reports the method development for the simultaneous determination of methylmercury (MeHg+) and inorganic mercury (iHg) species in seafood. The study focused on the extraction and quantification of MeHg+ by liquid chromatography coupled to on-line UV irradiation and cold vapour atomic fluorescence spectroscopy (LC-UV-HG-AFS), using HCl 4 mol L-1 as extractant agent.
|Comprehensive and Confident Identification of Narcotics, Steroids, and Pharamaceuticals in Urine|
David E. Alonso, Petra Gerhards, Charles Lyle, and Joe Binkley
-GC-HRT analysis provides an effectual “molecular profile” of samples
-Confident compound identification through spectral similarity searches & robust formula determinations for fragment, molecular and adduct ions
|Leveraging CI-H Mass Defect Plots for the Identification of Halogenated Organic Contaminants|
Jonathan D. Byer, Mehran Alaee, Karl Jobst, Grazina Pacepavicius, Joe Binkley
A number of legacy contaminants and other pesticides, as well as a number of previously unknown compounds were tentatively identified in the pooled sample. Cl-H mass defect plots are a useful tool for filtering through complex data for the identification of halogenated contaminants. This technique functions as a screening tool for the identification of unknowns, and in the future, may be used as a form of fingerprinting to compare samples.
|Flash Pyrolysis Coupled to GCxGC-TOFMS and GC-High Resolution TOFMS for Characterization of Crude Oil and Petroleum Fractions|
Clecio F. Klitzke, Joe Binkley, Jeffrey Patrick
The pyrolysis of asphaltenes from discrete crude oil samples shows distinct composition in terms of light and heavy aromatic hydrocarbons and alkyldibenzo-thiophenes. The use of Py–GC×GC–TOFMS is crucial for the determination of isomeric composition, and Py–GC–HRTOFMS with high resolution and high mass accuracy complements the identification by unequivocal chemical formula assignments. The study of the relationships of the crude oil and asphaltene composition are in progress.
|Analysis of Low Levels of Bisphenol A (BPA) in Canned Broths|
Ken G. Espenschied, Michael Ye, Olga I. Shimelis, and Christine Dumas
Bisphenol A (BPA) is a primary monomer used in the manufacture of many plastics and epoxies. Some of these plastics are used as beverage containers and as liners and sealants for metal food containers. Because of BPA’s potential to act as an endocrine disrupter at low concentrations in humans, regulations have been enacted regarding BPA concentrations in food and beverages sold for human consumption.
|Fast and Efficient Analysis of Polynuclear Aromatic Hydrocarbons in Edible Oils Using Dual-Layer SPE|
Christine Dumas and Katherine Stenerson
A new dual-layer cartridge for the efficient extraction of PAHs from edible oils