A Quantum Spin Liquid
Scientists from Boston College and Harvard turned to copper to create a first-of-its-kind iridate -- Cu2IrO3 -- where the natural magnetic order is disrupted, a state known as geometric frustration. Credit: Boston College.
Researchers from Boston College and Harvard have created an elusive honeycomb-structured material capable of frustrating the magnetic properties within it in order to produce a chemical entity known as "spin liquid," long theorized as a gateway to the free-flowing properties of quantum computing, according to a new report in the Journal of the American Chemical Society.
The first-of-its-kind copper iridate metal oxide - Cu2IrO3 - is one where the natural magnetic order is disrupted, a state known as geometric frustration, said Boston College Assistant Professor of Physics Fazel Tafti, a lead author of the study, titled Cu2IrO3: a new magnetically frustrated honeycomb iridate.
The copper iridate is an insulator - its electrons are immobilized in the solid - but they can still transport a magnetic moment known as "spin". The transport of free spins in the material allows for a flow of quantum information.
The Kitaev model, proposed in 2006 by Cal Tech Professor of Physics Alexei Kitaev, states that a hexagonal honeycomb structure offered a promising route to geometric frustration and therefore, to quantum spin liquid.
Only two honeycomb lattice have been successfully developed in an attempt to fulfill Kitaev's model: a lithium iridate (Li2IrO3) and a sodium iridate (Na2IrO3). Yet both fell short of achieving an ideal spin liquid due to magnetic ordering, said Tafti, who co-authored the paper with Boston College post-doctoral researchers Mykola Abramchuk and Jason W. Krizan, BC Adjunct Professor of Chemistry and Director of Advanced Chemistry Laboratories Kenneth R. Metz, and Harvard's David C. Bell and Cigdem Ozsoy-Keskinbora.
Tafti and his team turned to copper due to its ideal atomic size, which is between lithium and sodium. Their studies in x-ray crystallography found subtle flaws in the honeycombs formed in the lithium and sodium iridates. The team swapped copper for sodium in what Tafti termed a relatively simple "exchange" reaction. The effort produced the first oxide of copper and iridium, Tafti said.
"Copper is ideally suited to the honeycomb structure," said Tafti. "There is almost no distortion in the honeycomb structure."
A decade after the original prediction of quantum spin liquid on a honeycomb lattice by Kitaev, the young team of scientists from Boston College succeeded in making a material that almost exactly corresponds to the Kitaev model, Tafti said.
Tafti's lab will pursue the "exchange" chemistry path to make new forms of honeycomb materials with more exotic magnetic properties, he said.
This article has been republished from materials provided by Boston College. Note: material may have been edited for length and content. For further information, please contact the cited source.
Mykola Abramchuk, Cigdem Ozsoy-Keskinbora, Jason W. Krizan, Kenneth R. Metz, David C. Bell, Fazel Tafti. Cu2IrO3: A New Magnetically Frustrated Honeycomb Iridate. Journal of the American Chemical Society, 2017; DOI: 10.1021/jacs.7b06911.
Bacteria Eats Greenhouse Gas with a Side of ProteinNews
With the ability to leech heavy metals from the environment and digest a potent greenhouse gas, methanotrophic bacteria pull double duty when it comes to cleaning up the environment. Scientists have identified two never-before-studied proteins, MbnB and MbnC, as partially responsible for the bacteria’s capabilities.READ MORE
Microgel Mops Up Toxins Without Harming "Good" BacteriaNews
While it’s easy to blame the bacteria during intestinal infections, it’s actually the toxins the bacteria produce that trigger inflammation, diarrhea, fever and cramps. Treatments typically include indiscriminate antibiotics that slaughter health-promoting gut bacteria along with disease-causing microbes. Researchers now report the development of a microgel scavenger that targets toxins instead of bacteria.READ MORE
Rechargable Antibacterial Coating - Just Add Bleach!News
Stainless steel is the gold standard for kitchen appliances and cookware, described as modern and sleek. But bacteria can grow on stainless steel surfaces, contaminating food. Current coatings available on the market are pricey and potentially harmful, so scientists have now developed an affordable specialized polymer coating for such surfaces that they can recharge with bleach treatments.READ MORE