New Method to Analyze the Scattering of Electrons in Nanocrystals
Scientists from the Institute of Physics of the CAS have developed a new method to analyze the scattering of electrons in nanocrystals. The method is so accurate that it can be used to detect hydrogen. Important progress has also been made also in the field of analysis of nanocrystals, thanks to the development of new techniques exploiting scattering (diffraction) of electrons on crystals.
So far, however, this method provided only approximate information and did not allow the determination of all necessary details of the crystal structures. An international team led by the scientists from Department of Structure Analysis of the Institute of Physics of CAS has therefore spent last few years developing a method, which would lift this limitation and improve the accuracy of structure analysis by electron diffraction. The goal has been achieved by using advanced computing techniques and development of new algorithms for data processing.
The success of the new method is demonstrated by determination of the positions of the lightest of all atoms, atoms of hydrogen. A hydrogen atom contains only one proton and one electron, and its signal in electron diffraction is the weakest signal among all chemical elements. A reliable detection of hydrogen atom positions is generally considered as one of the most difficult tasks in structure determination, and it was so far essentially impossible with electron diffraction.
The work was conducted in collaboration with scientists from CNRS Caen, France, and it was published in the prestigious journal Science. Within the work, two structures were analyzed – an organic compound paracetamol, which is the active ingredient of several pain killing and fever reducing drugs, and hydrated cobalt aluminophosphate (CAP). The latter was selected as a representative of the class of framework materials, which are commonly used in chemical industry as sorbents and catalysts. In both cases all hydrogen positions in the crystal structure were found.
The method brings a qualitative progress in the capacity of analysis of crystal structures. Given the wide applications of crystallography in natural science, the method has the potential to contribute to the development of many scientific fields.
Palatinus, L., Brázda, P., Boullay, P., Perez, O., Klementová, M., Petit, S., Mintova, S. (2017). Hydrogen positions in single nanocrystals revealed by electron diffraction. Science, 355(6321), 166–169. doi:10.1126/science.aak9652
This article has been republished from materials provided by the Czech Academy of Sciences. Note: material may have been edited for length and content. For further information, please contact the cited source.
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