New Support for HPLC Based on Silica Coated with Alumina Particles
News Feb 26, 2014
A new material based on silica coated with alumina nanoparticles was proposed for use as a chromatographic support for reversed-phase high-performance liquid chromatography. Alumina nanoparticles were synthesized by a sol-gel process in reversed micelles composed of sodium bis(2-ethylhexyl)sulfosuccinate, and the support material was formed by the self-assembly of alumina layers on silica spheres. Spectroscopic and (29)Si nuclear magnetic resonance results showed evidence of chemical bonds between the alumina nanoparticles and the silica spheres, while morphological characterizations showed that the aluminized silica maintained the morphological properties of silica desired for chromatographic purposes after alumina incorporation. Stability studies indicated that bare silica showed high dissolution (∼83%), while the aluminized silica remained practically unchanged (99%) after passing one liter of the alkaline mobile phase, indicating high stability under alkaline conditions. The C18 bonded aluminized silica phase showed great potential for use in high-performance liquid chromatography to separate basic molecules in the reversed-phase mode.
The article is published online in the journal Analytical Sciences and is free to access.
Deep-Sea Conditions Impact Oil DegradationNews
Degradation rates of oil were slower in the dark and cold waters of the depths of the Gulf of Mexico than at surface conditions, according to an international team of geoscientists trying to understand where the oil went during the Deepwater Horizon oil spill.READ MORE
Lake gives Clues to Earth's Ancient AtmosphereNews
A sample of ancient oxygen, teased out of a 1.4 billion-year-old evaporative lake deposit in Ontario, provides fresh evidence of what the Earth’s atmosphere and biosphere were like during the interval leading up to the emergence of animal life.READ MORE