We've updated our Privacy Policy to make it clearer how we use your personal data.

We use cookies to provide you with a better experience. You can read our Cookie Policy here.

Solar Cell Performance Predicted With Terahertz and Microwave Spectroscopy

Solar Cell Performance Predicted With Terahertz and Microwave Spectroscopy

Solar Cell Performance Predicted With Terahertz and Microwave Spectroscopy

Solar Cell Performance Predicted With Terahertz and Microwave Spectroscopy

In the femtosecond laser laboratory of Dr. Dennis Friedrich at HZB, the transport properties of semiconductors can be determined using terahertz or microwave spectroscopy. For this purpose, a laser light pulse first excites the charge carriers in the material, which are then irradiated with electromagnetic waves (either THz or Microwave) and absorb some of them. Credit:HZB.
Read time:

Want a FREE PDF version of This News Story?

Complete the form below and we will email you a PDF version of "Solar Cell Performance Predicted With Terahertz and Microwave Spectroscopy"

First Name*
Last Name*
Email Address*
Company Type*
Job Function*
Would you like to receive further email communication from Technology Networks?

Technology Networks Ltd. needs the contact information you provide to us to contact you about our products and services. You may unsubscribe from these communications at any time. For information on how to unsubscribe, as well as our privacy practices and commitment to protecting your privacy, check out our Privacy Policy

Many semiconducting materials are possible candidates for solar cells. In recent years, perovskite semiconductors in particular have attracted attention, as they are both inexpensive and easy to process and enable high efficiencies. Now a study with 15 participating research institutions shows how terahertz (TRTS) and microwave spectroscopy (TRMC) can be used to reliably determine the mobility and lifetime of the charge carriers in new semiconducting materials. Using these measurement data it is possible to predict the potential efficiency of the solar cell in advance and to classify the losses in the finished cell.   

The most important properties of a semiconductor to be used as a solar cell include the mobility and lifetime of electrons and "holes". Both quantities can be measured without contacts with spectroscopic methods using terahertz or microwave radiation. However, measurement data found in literature often differ by orders of magnitude. This has made it difficult to use them for reliable assessments of material quality.

Reference samples measured

"We wanted to get to the bottom of these differences, and contacted experts from a total of 15 international laboratories to analyse typical sources of error and problems with the measurements," says Dr. Hannes Hempel from the HZB team led by Dr. Thomas Unold. The HZB physicists sent reference samples produced by the team of Dr. Martin Stolterfoht at University Potsdam to each laboratory with the perovskite semiconductor compound (Cs,FA,MA)Pb(I,Br)3) optimised for stability.

Better data for better prediction

One result of the joint work is the significantly more precise determination of the transport properties with terahertz or microwave spectroscopy. "We could identify some neuralgic points that have to be considered before the actual measurements takes place, which allows us to arrive at significantly better agreement of the results," Hempel emphasises.   

Another result of the study: With reliable measurement data and a more advanced analysis, the characteristics of the solar cell can also be calculated more precisely. "We believe that this analysis is of great interest for photovoltaic research, because it predicts the maximum possible efficiency of the material in a solar cell and reveals the influence of various loss mechanisms, such as transport barriers," says Unold. This applies not only to the material class of perovskite semiconductors, but also to other new semiconducting materials, which can thus be tested more quickly for their potential suitability.

Reference: Hempel H, Savenjie TJ, Stolterfoht M, et al. Predicting Solar Cell Performance from Terahertz and Microwave Spectroscopy. Adv Ener Mat. n/a(n/a):2102776. doi:10.1002/aenm.202102776

This article has been republished from the following materials. Note: material may have been edited for length and content. For further information, please contact the cited source.