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Long-Lasting, Cobalt-Free Li-Ion Batteries Created

Lithium-ion button batteries in their packaging.
Credit: Alexei / Pixabay.

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In a discovery that could reduce or even eliminate the use of cobalt – which is often mined using child labor – in the batteries that power electric cars and other products, scientists at the University of California, Irvine have developed a long-lasting alternative made with nickel.


“Nickel doesn’t have child labor issues,” said Huolin Xin, the UCI professor of physics & astronomy whose team devised the method, which could usher in a new, less controversial generation of lithium-ion batteries. Until now, nickel wasn’t a practical substitute because large amounts of it were required to create lithium batteries, he said. And the metal’s cost keeps climbing.


To become an economically viable alternative to cobalt, nickel-based batteries needed to use as little nickel as possible.


“We’re the first group to start going in a low-nickel direction,” said Xin, whose team published its findings in the journal Nature Energy. “In a previous study by my group, we came up with a novel solution to fully eliminate cobalt. But that formulation still relied on a lot of nickel.”


To solve that problem, Xin’s team spent three years devising a process called “complex concentrated doping” that enabled the scientists to alter the key chemical formula in lithium-ion batteries as easily as one might adjust seasonings in a recipe.

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The doping process, Xin explained, eliminates the need for cobalt in commercial components critical for lithium-ion battery functioning and replaces it with nickel.


“Doping also increases the efficiency of nickel,” said Xin, which means EV batteries now require less nickel to work – something that will help make the metal a more attractive alternative to cobalt-based batteries.


Xin said he thinks the new nickel chemistry will quickly start transforming the lithium-ion battery industry. Already, he said, electric vehicle companies are planning to take his team’s published results and replicate them.


“EV makers are very excited about low-nickel batteries, and a lot of EV companies want to validate this technique,” Xin said. “They want to do safety tests.”


Reference: Zhang R, Wang C, Zou P, et al. Long-life lithium-ion batteries realized by low-Ni, Co-free cathode chemistry. Nat Energy. Published online June 12, 2023:1-8. doi:10.1038/s41560-023-01267-y



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